Efficient PFAS removal from contaminated soils through combined washing and adsorption in soil effluents

This study investigates soil washing as a viable strategy to remove poly- and perfluoroalkyl substances (PFAS) from contaminated soils using various washing agents including water, methanol, ethanol, and cyclodextrin ((2-Hydroxypropyl)-β-cyclodextrin HPCD)). Water was less effective (removing only 30 % of PFAS), especially for long-chain hydrophobic PFAS. Methanol (50 % v/v) or HPCD (10 mg g^-1 soil) achieved > 95 % PFAS removal regardless of PFAS type, soil size fraction (0-400 µm or 400-800 µm), or experimental setups (batch or column, at liquid/solid (L/S) = 1). Column optimization studies revealed improved efficiency at L/S = 10 with diluted washing solutions, where HPCD exhibited rapid PFAS mobilization even at lower concentrations (1 mg mL^-1). We then applied a first-order decay model to effectively predict PFAS breakthrough curves and mobilization within soil columns. Subsequent treatment of wash effluents by activated carbon and biochar effectively reduced PFAS concentrations below detection limits. The performance of both soil washing and subsequent adsorption was found to depend strongly on the specific characteristics of PFAS compounds. These findings highlight the significant potential of methanol and HPCD in soil washing and the effectiveness of integrated soil washing and adsorption for optimizing PFAS removal.