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Updated: Jun 21, 2025

Exfoliation and Analysis of Large-area, Air-Sensitive Two-Dimensional Materials
Published on: January 5, 2019
Electrochemical exfoliation of graphene from pencil lead
Natchanon Jiwarawat1, Thapan Leukulwatanachai1, Kunbhass Subhakornphichan1
1International School of Engineering, Nano-Engineering, Faculty of Engineering, Chulalongkorn University, Bangkok, 10330, Thailand.
Abstract:
Addressing an ever-increasing demand for graphene in recent years, simple, accessible, and effective graphene synthesis methods are essential. One of such methods is to use a highly oriented pyrolytic graphite (HOPG) to perform an electrochemical exfoliation. While this is one of the simplest and most cost-effective methods, the limited availability and price of HOPG hinders its usage. Our study proposed a simple and economical electrochemical exfoliation of pencil lead, producing graphene with properties comparable to that produced from HOPG. The electrical properties are determined by depositing graphene onto a screen-printed electrode. Graphene from pencil leads can achieve an electrical resistance as low as 1.86 kΩ, marking over 80% improvement in electrical performance compared to bare electrodes. This finding provides an alternative for the synthesis of graphene, increasing its availability and the cost-effectiveness as well as contributing towards a potential commercialization of the method in the future.

