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Updated: Jun 21, 2025

Dynamic Electrochemical Measurement of Chloride Ions
Published on: February 5, 2016
Factors Influencing Chloride Ion Diffusion in Reinforced Concrete Structures
Qiulang Xu1, Bin Liu2, Lin Dai1
1Guangxi Nanbin Highway Construction and Development Co., Ltd., Nanning 530400, China.
Abstract:
Reinforced concrete structures are prone to the corrosion of steel bars when exposed to chloride-rich environments, which can severely impact their durability. To address this issue, a comprehensive understanding of the factors influencing chloride ion diffusion in concrete is essential. This paper provides a summary of recent domestic and foreign research on chloride ion transport in concrete, focusing on six key factors: water-binder ratio, additive content, crack width, ambient temperature, relative humidity, and dry-wet cycles. The findings show that the diffusion coefficient of chloride ions in concrete increases with a higher water-binder ratio and decreases with increased additive content. Additionally, wider cracks result in a greater diffusion of chloride ions. The permeability resistance of concrete to chloride ions decreases with rising temperature and humidity, and dry-wet cycles further accelerate the diffusion of chloride ions. The article concludes by discussing various anti-corrosion measures, such as the use of corrosion inhibitors, surface coatings, and electrochemical treatments, to ensure the longevity of the structure. Finally, directions for future research are proposed.
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