Synthesis of ternary geopolymers using prediction for effective solidification of mercury in tailings

This study used steel slag, fly ash, and metakaolin as raw materials (SFM materials) to create silica-alumina-based geopolymers that can solidify Hg²⁺ when activated with sodium-based water glass. The experiments began with a triangular lattice point mixing design experiment, and the results were fitted, analyzed, and predicted. The optimum SFM material mass ratio was found to be 70% steel slag, 25% fly ash, and 5% metakaolin. The optimum modulus of the activator was identified by comparing the unconfined compressive strength and solidifying impact on Hg²⁺of geosynthetics with different modulus. The SFM geopolymer was then applied in the form of potting to cure the granulated mercury tailings. The inclusion of 50% SFM material generated a geosynthetic that reduced mercury transport to the surface soil by roughly 90%. The mercury concentration of herbaceous plant samples was also reduced by 78%. It indicates that the SFM material can effectively attenuate the migration transformation of mercury. Finally, characterization methods such as XPS and FTIR were used to investigate the mechanism of Hg²⁺ solidification by geopolymers generated by SFM materials. The possible solidification mechanisms were proposed as alkaline environment-induced mercury precipitation, chemical bonding s, surface adsorption of Hg²⁺ and its precipitates by the geopolymer, and physical encapsulation.