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Updated: Jun 21, 2025

Synthesis of Functionalized Magnetic Nanoparticles, Their Conjugation with the Siderophore Feroxamine and its Evaluation for Bacteria Detection
Published on: June 16, 2020
Peroxymonosulfate activation by cobalt-doped ferromanganese magnetic oxides through singlet oxygen and radical
Fengchun Li1, Yawei Gu1,2, Luwei Zhai1
1School of Environmental Science and Engineering, Qilu University of Technology (Shandong Academy of Sciences) Jinan 250353 China gyw@qlu.edu.cn jwq@qlu.edu.cn.
Abstract:
In this paper, cobalt-doped MnFe2O4 (CMFO-0.4) with oxygen vacancies was successfully synthesised by the sol-gel method and applied as a high-performance catalyst for the activation of peroxomonosulfate (PMS). The catalyst showed an excellent catalytic effect for the degradation of sulfadiazine (SDZ) by activated PMS, and the degradation rate can reach 100% in 10 minutes. The effects of different conditions on the degradation of SDZ were investigated, and it was determined that the optimal concentrations of catalyst and PMS were 0.2 g L-1 and 1 mM, respectively, and had good degradation effects in the pH 5-11 range. Free radical quenching experiments, XPS, and electron paramagnetic resonance (EPR) analyses revealed the presence of hydroxyl radicals (˙OH), sulphate radicals (SO4˙-), singlet oxygen (1O2), and superoxide radicals (˙O2 -) in the CMFO-0.4/PMS system, with 1O2 being the main reactive oxygen species (ROS). In addition, CMFO-0.4 has good reusability and adaptability to the presence of other substances.
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