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Updated: Jun 20, 2025

Synthesis of Cyclic Polymers and Characterization of Their Diffusive Motion in the Melt State at the Single Molecule Level
Published on: September 26, 2016
Diffusion with a broad class of stochastic diffusion coefficients.
Go Uchida1,2, Hitoshi Washizu2, Hiromi Miyoshi1
1Department of Mechanical Systems Engineering, <a href="https://ror.org/00ws30h19">Tokyo Metropolitan University</a>, Tokyo 1920397, Japan.
Diffusion with stochastic diffusion coefficients (DCs) leads to non-Gaussian, heavy-tailed behavior in finite times. However, it converges to Gaussian in the long term, with convergence speed dependent on the DC
Area of Science:
- Physics
- Physical Chemistry
- Biophysics
Background:
- Brownian motion is a fundamental model for diffusion.
- Stochastic diffusion coefficients (DCs) introduce complexity beyond standard models.
- Understanding anomalous diffusion is crucial in various scientific fields.
Purpose of the Study:
- Investigate diffusion properties with a broad class of stochastic diffusion coefficients.
- Characterize the propagator's behavior in finite and long time limits.
- Compare diffusion with stochastic DCs to deterministic DCs and fractional Brownian motion.
Main Methods:
- Analysis of diffusion processes with stochastic DCs, distinct from subordination approaches.
- Mathematical derivation and characterization of the particle propagator.
- Examination of ergodicity and its impact on propagator convergence.
Main Results:
- The propagator exhibits non-Gaussian and heavy-tailed characteristics for finite diffusion times.
- Particles with stochastic DCs can diffuse farther than those with deterministic DCs or fractional Brownian motion over finite times.
- For ergodic stochastic DCs, the propagator converges to a Gaussian distribution in the long time limit.
Conclusions:
- Stochastic diffusion coefficients lead to significant deviations from standard diffusion models at finite times.
- The long-time behavior of diffusion with stochastic DCs is predictable and Gaussian, with convergence rate influenced by the DC's autocovariance.
- This study provides new insights into anomalous diffusion phenomena.
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