Groundwater irrigation induced variations in DOM fluorescence and arsenic mobility

Dissolved organic matter (DOM) plays a predominant role in groundwater arsenic (As) mobility. However, the temporal-spatial variations in DOM fluorescent characteristics and their effects on As mobility induced by groundwater irrigation remain unclear. To address these issues, groundwater from multilevel and irrigation wells in Zones I and II (with low- and high-As groundwater irrigation, respectively) from the Hetao Basin, China, were monitored in both non-irrigation (NIG) and irrigation (IG) seasons. Upon irrigation, the irrigation return increased the relative abundance of protein- and humic-like DOM in shallow groundwater from Zone I with Ca-type groundwater and Zone II with Na-type groundwater irrigation, respectively. The introduced dissolved oxygen by irrigation return decreased As concentrations by 22 % and 6 % on average in shallow groundwater from Zones I and II, respectively. However, the pumping-induced lateral recharge of lower- and higher-As groundwater led to an average 17 % decrease and 38 % increase in As concentrations in deeper groundwater from the two zones, respectively. The increased degradation of protein-like DOM may also contribute to the elevated As concentrations in deep groundwater from Zone II. The study provides insights into the dependence of irrigation-induced variations in DOM fluorescence and As concentrations on geochemicals of irrigation groundwater and aquifer hydrogeological conditions.