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Updated: Jun 20, 2025

All-electronic Nanosecond-resolved Scanning Tunneling Microscopy: Facilitating the Investigation of Single Dopant Charge Dynamics
Published on: January 19, 2018
Reverse Intersystem Crossing Dynamics in Vibronically Modulated Inverted Singlet-Triplet Gap System: A Wigner Phase
Pijush Karak1, Pradipta Manna1, Ambar Banerjee2
1Department of Chemistry, University of Calcutta, 92 A. P. C. Road, Kolkata 700009, West Bengal, India.
Abstract:
We inspect the origin of the inverted singlet-triplet gap (INVEST) and slow change in the reverse intersystem crossing (rISC) rate with temperature, as recently observed. A Wigner phase space study reveals that, though INVEST is found at equilibrium geometry, variation in the exchange interaction and the doubles-excitation for other geometries in the harmonic region leads to non-INVEST behavior. This highlights the importance of nuclear degrees of freedom for the INVEST phenomenon, and in this case, geometric puckering of the studied molecule determines INVEST and the associated rISC dynamics.
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