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Investigation of the Relationship between Quantum Yield, Charge-Transfer State, and Structure of the Ligands in
Gi Rim Han1, Ohyun Kwon2, Sungmin Kim2
1Department of Chemistry, Seoul National University, Gwanak-ro 1, Gwanak-gu, Seoul 08826, Republic of Korea.
Abstract:
Iridium(III) organometallic complexes have been a key component in commercialization of organic light-emitting diodes, but the direct relationship between their structural features and photophysical properties has not yet been fully established. Here, combined experimental and theoretical studies are carried out to elucidate the main factors governing the quantum efficiency of red phosphorescent emitters by using two heteroleptic iridium(III) complexes with high geometrical similarity. It is found that two red-emitting heteroleptic iridium complexes differing only in the steric direction of phenylquinoline (pq) and phenylisoquinoline (piq) ligands, annotated Red-pq and Red-piq, show clearly different degrees of distortion of the ligand geometry in the excited state, which leads to the higher quantum yield of Red-piq than that of Red-pq. This larger distortion of the piq ligand causes more suppressed nonradiative decay of Red-piq than that of Red-pq which is the important factor governing the higher quantum yield of Red-piq.
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