Ironstone and red mud barriers to reduce subsurface movement of soil phosphorus

Loss of phosphorus in seepage may contribute to eutrophication of downstream water bodies. This study examined the potential use of pedogenic ironstone and untreated red mud (bauxite refining residue) as P sorbents in a permeable reactive barrier (PRB) to mitigate such loss. Effects of ironstone and red mud on P sorption (batch), transport (columns), saturated hydraulic conductivity (K_S), and growth of common bermudagrass (Cynodon dactylon; greenhouse) were examined. Both materials had sorption maxima of ∼30 mmol P kg^-1 or about five times that of a P-enriched sandy soil; however, sorption by red mud greatly increased with decreasing pH. Transport of P through columns of ironstone and red mud (diluted with nonreactive sand) was similar and slower compared to soil + sand. However, when red mud was mixed with soil, increased sorption at lower pH resulted in greater P retention compared to ironstone + soil (76% vs. 13%). Although addition of ironstone to soil up to 20% did not reduce K_S, red mud at even 5% did. Soil amendment with red mud increased bermudagrass growth and P uptake. Given long-term neutralization of red mud in an acidic soil and increased P sorption, it may be suitable in a PRB if incorporated at a low rate and/or co-incorporated with a coarser material.