Well-Ordered Nanoparticles/Block Copolymer Nanosheets with a Controllable Location of Nanoparticles

Precisely controlling the spatial distributions and arrangements of metal nanoparticles (NPs) into block copolymers is of great importance for fabricating novel nanomaterials with the desired optical and electronic properties. Herein, we develop a simple yet versatile strategy to prepare organic/inorganic nanosheets formed by the coassembly of polystyrene-block-poly(4-vinylpyridine) (PS-b-P4VP) and PS tethered gold nanoparticles (AuNPs@PS) within emulsion droplets. The arrangement of the AuNPs@PS building blocks within the block copolymers (BCP)/AuNPs nanosheets can be adjusted by tuning the effective size ratio (λ_eff), which can be controlled by the core diameter of the AuNPs and the molecular weight of the PS. Furthermore, the content of the AuNPs is also another essential parameter to manipulate the structures of the nanosheets with the specific λ_eff. Thus, the BCP/AuNPs hybrid nanosheets with controllable distributions and arrangements of the AuNPs were successfully prepared via tuning of λ_eff and the content of AuNPs. This study provides a facile way to fabricate well-ordered hybrid nanosheets.