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The distribution law or Nernst's distribution law is the law that governs the distribution of a solute between two immiscible solvents. This law, also known as the partition law, states that if a solute is added to the mixture of two immiscible solvents at a constant temperature, the solute is distributed between the two solvents in such a way that the ratio of solute concentrations in the solvents remains constant at equilibrium.
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How to Partition a Quantum Observable.

Caleb Merrick Webb1, Charles Allen Stafford1

  • 1Department of Physics, University of Arizona, Tucson, AZ 85721, USA.

Entropy (Basel, Switzerland)
|July 26, 2024
PubMed
Summary
This summary is machine-generated.

We introduce a Hilbert space partition for open quantum systems, defining an entropy current that governs local entropy fluctuations. This method ensures thermodynamic consistency, unlike other partitioning approaches.

Keywords:
entropyopen quantum systempartitioningthermodynamics

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Area of Science:

  • Quantum Mechanics
  • Statistical Mechanics
  • Thermodynamics

Background:

  • Open quantum systems exhibit complex dynamics influenced by their environment.
  • Understanding local entropy evolution is crucial for non-equilibrium statistical mechanics.
  • Existing formalisms may not consistently describe entropy partitioning.

Purpose of the Study:

  • To develop a consistent framework for partitioning quantum observables in open systems.
  • To analyze the local evolution of von Neumann entropy for independent quantum particles.
  • To investigate the relationship between entropy current and heat current under specific conditions.

Main Methods:

  • Partitioning of the Hilbert space or configuration space.
  • Derivation of an inhomogeneous continuity equation for observables.
  • Application to the local evolution of von Neumann entropy.
  • Analysis of system-reservoir coupling symmetry.

Main Results:

  • A partition of observables is inherited from Hilbert space division.
  • Local entropy fluctuations are governed by an entropy current operator.
  • Entropy current is equivalent to heat current for symmetrically coupled systems.
  • Asymmetric coupling partitions lead to entropy divergence.

Conclusions:

  • Hilbert-space partitioning provides a thermodynamically consistent framework for von Neumann entropy.
  • The derived entropy current operator governs local entropy changes.
  • This formalism clarifies the distinction between partitioned entropy and entanglement entropy production.