Synthesis and Characterization of ZnO and TiO₂ Hybrid Coatings for Textile UV Anti-Aging Protection

The aim of this study was to prepare and characterize thin hybrid films on polyurethane-coated knitted fabrics and to achieve satisfactory color fastness to artificial light. Sol-gel-derived hybrid thin films were deposited via the dip-coating of 3-glycidoxypropiltrimethoxysilane. Titanium dioxide (TiO₂) and zinc oxide (ZnO) nanopowders were added to compensate for the insufficient aging resistance, which manifests itself in low color fastness and is one of the most frequent complaints from manufacturers of coated marine fabrics (yachts, boats, etc.). The optimum processing conditions were determined by varying the concentration of precursors and auxiliaries, the mass concentration of TiO₂ and ZnO nanopowders, the drawing speed, and the methods and process of fabric treatment. The hybrid films were also characterized using scanning electron microscopy and Fourier transform infrared spectroscopy with attenuated total internal reflection, while Spectraflash SF 300 investigated color fastness. After 300 h of exposure in a xenon chamber, the thin hybrid films showed good color fastness and good resistance to washing cycles. The sol-gel treatment proved to be a successful answer to the manufacturers' need for the post-treatment of polyurethane-coated knitted fabrics against UV radiation for use in the marine sector (yachts, speedboats, etc.).