High-density sampling of soil heavy metals in the upper Bailang River basin: contamination characteristics, sources,...

Heavy metals (HMs) seriously harm soil environment and threaten crop quality and human health. The aim of the study was to investigate the characteristics, quantify the sources and assess the risks of HMs in soil of upper Bailang River Basin (UBRB). The results indicated that the soils in UBRB were at a non-polluted level and posed a low ecological risk to the environment as a whole. The main pollutants were Ni and Cr obtained by indices P_i and I_geo. Based on the consideration of toxicity, the fuzzy comprehensive evaluation model and E_i index revealed that Hg and Cd were dominating pollutants and ecological risk factors of soil in UBRB. The positive matrix factorization model ascertained five potential sources of soil HMs, namely, plastic processing, energy activities, parent material, transportation and agriculture mixed source and industrial manufacturing, with contribution rates of 17%, 7%, 15%, 29% and 32%, respectively. Natural source primarily determined the non-carcinogenic risk for all populations, accounting for about 43% of the total risk. Industrial manufacturing mainly determined the carcinogenic risk, accounting for about 45%. For adults, the risk was acceptable for most of the sample points. For children, potential non-carcinogenic risks were present in 13.19% of the sample sites, which were mainly located in the west, and unacceptable carcinogenic risks were present in 57.21% of the sample sites, which were mainly concentrated in the western and central parts.