Mo₂C-Co heterostructure with carbon nanosheets decorated carbon microtubules: Different means for high-performance...

The practical applications of lithium sulfur batteries (LSBs) are hindered by notorious shuttle effect and sluggish conversion kinetics of intermediate polysulfides. Herein, Mo₂C-Co heterogeneous particles decorated two-dimensional (2D) carbon nanosheets grown on hollow carbon microtubes (CCC@MCC) are synthesized. Three-dimensional (3D) carbon framework with Mo₂C-Co heterogeneous particles combines the conductivity, adsorption and catalysis, effectively trapping and accelerating the conversion of polysulfides. As evidenced experimentally, the hetero-structured Mo₂C-Co with high Li⁺ diffusion coefficient enables uniform precipitation and complete oxidation of Li₂S. Meanwhile, CCC@MCC is found to have multiple application possibilities for lithium-sulfur batteries. As an interlayer, the cells deliver an excellent capacity of 881.1 mAh/g at 2C and still retain 438.2 mAh/g after 500 cycles under the low temperature of 0 ℃. As a sulfur carrier, the cell with a sulfur loading of 7.0 mg cm^-2 exhibits a high area capacity of 5.3 mAh cm^-2. This work provides an effective strategy to prepare heterostructured material and imaginatively exploit the application potential of it.