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Related Concept Videos

Free-Radical Chain Reaction and Polymerization of Alkenes02:35

Free-Radical Chain Reaction and Polymerization of Alkenes

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The conversion of alkenes to macromolecules called polymers is a reaction of high commercial importance. The structure of the polymer is defined by a repeating unit, while the terminal groups are considered insignificant. The average degree of polymerization represents the number of repeating units in the polymer molecule and is denoted by the subscript n.
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Abrasion Resistance of Concrete01:23

Abrasion Resistance of Concrete

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Abrasion resistance is an essential characteristic of concrete that determines its durability and longevity under various wear conditions. Concrete surfaces are vulnerable to different types of abrasion. For instance, surfaces may wear down due to the constant movement of vehicles or be eroded by solids carried in water, as seen in concrete canal linings. Specific tests are conducted to measure the abrasion resistance of concrete.
One such test is the revolving disc test, where three plates...
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Polymer Classification: Architecture01:14

Polymer Classification: Architecture

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Polymers are classified as linear or branched on the basis of their chain architecture. The polymer chains in linear polymers have a long chain-like structure with minimal to no branching at all. Even if a polymer features large substituent groups on the monomer, which appear as branches to the skeleton, it is not considered a branched polymer. A branched polymer contains secondary polymer chains that arise from the main polymer chain. The branching occurs when the polymer growth shifts from...
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Rolling Resistance01:21

Rolling Resistance

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When a solid cylinder rolls steadily on a rigid surface, the normal force applied by the surface on the cylinder is perpendicular to the tangent at the contact point. However, since no materials are entirely rigid, the surface's reaction to the cylinder involves a range of normal pressures.
For instance, imagine a hard cylinder rolling on a comparatively soft surface. The cylinder's weight compresses the surface beneath it. As the cylinder moves, the material in front of it slows down...
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Olefin Metathesis Polymerization: Ring-Opening Metathesis Polymerization (ROMP)01:16

Olefin Metathesis Polymerization: Ring-Opening Metathesis Polymerization (ROMP)

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Ring-opening metathesis polymerization or ROMP involves strained cycloalkenes as starting materials. The mechanism of ROMP proceeds by reacting cycloalkene with Grubbs catalyst to give metallacyclobutane intermediate which undergoes a ring-opening reaction to form new carbene. The new carbene reacts with another molecule of cycloalkene. Repetition of these steps leads to the formation of an unsaturated open-chain polymer product. All these steps are reversible, however, relieving the ring...
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Olefin Metathesis Polymerization: Overview01:13

Olefin Metathesis Polymerization: Overview

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Recently, the development of olefin metathesis polymerization advanced the field of polymer synthesis. Simply put, the reorganization of substituents on their double bonds between two olefins in the presence of a catalyst is known as the olefin metathesis reaction. The use of metathesis reaction for polymer synthesis is called olefin metathesis polymerization.
Ruthenium-based Grubbs catalyst is the most commonly used catalyst for olefin metathesis polymerization. Grubbs catalyst consists...
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  1. Home
  2. Research Domains
  3. Engineering
  4. Environmental Engineering
  5. Air Pollution Modelling And Control
  6. Characterization Of Emissions From Rubber Modified Asphalt And Their Impact On Environmental Burden: Insights Into Composition Variability And Hazard Assessment.
  1. Home
  2. Research Domains
  3. Engineering
  4. Environmental Engineering
  5. Air Pollution Modelling And Control
  6. Characterization Of Emissions From Rubber Modified Asphalt And Their Impact On Environmental Burden: Insights Into Composition Variability And Hazard Assessment.

Related Experiment Video

Advanced Self-Healing Asphalt Reinforced by Graphene Structures: An Atomistic Insight
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Advanced Self-Healing Asphalt Reinforced by Graphene Structures: An Atomistic Insight

Published on: May 31, 2022

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Characterization of emissions from rubber modified asphalt and their impact on environmental burden: Insights into composition variability and hazard assessment.

Lingwen Li1, Tao Zhou1, Liping Cao1

  • 1School of Transportation Science and Engineering, Harbin Institute of Technology, Harbin, Heilongjiang 150090, PR China.

Journal of Hazardous Materials
|July 30, 2024

View abstract on PubMed

Summary
This summary is machine-generated.
Keywords:
Asphalt fractionsAsphalt fumesEmission behaviorEnvironmental burden

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The Preparation and Properties of Thermo-reversibly Cross-linked Rubber Via Diels-Alder Chemistry
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Measuring Sub-23 Nanometer Real Driving Particle Number Emissions Using the Portable DownToTen Sampling System
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Measuring Sub-23 Nanometer Real Driving Particle Number Emissions Using the Portable DownToTen Sampling System

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Related Experiment Videos

Advanced Self-Healing Asphalt Reinforced by Graphene Structures: An Atomistic Insight
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The Preparation and Properties of Thermo-reversibly Cross-linked Rubber Via Diels-Alder Chemistry
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Measuring Sub-23 Nanometer Real Driving Particle Number Emissions Using the Portable DownToTen Sampling System
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Recycling tires into rubber modified asphalt (RMA) produces hazardous emissions. This study quantifies these emissions, finding polycyclic aromatic hydrocarbons (PAHs) are major contributors to ozone and aerosol formation.

Area of Science:

  • Environmental Science
  • Materials Science
  • Chemical Engineering

Background:

  • Rubber modified asphalt (RMA) offers a sustainable solution for waste tire recycling.
  • Concerns exist regarding hazardous fume emissions during RMA production and use.
  • Understanding emission characteristics is crucial for environmental risk assessment.

Purpose of the Study:

  • To analyze the emission behavior of RMA under thermal conditions, focusing on crumb rubber size.
  • To quantify Ozone Formation Potential (OFP) and Secondary Organic Aerosol Formation Potential (SOAFP).
  • To identify key pollutants and their sources contributing to environmental burden.

Main Methods:

  • Utilized a specialized apparatus to measure emissions from RMA.
  • Varied crumb rubber size and thermal exposure duration.
Rubber particle size
  • Quantified emissions of hydrogen sulfide (H₂S), volatile organic compounds (VOCs), and polycyclic aromatic hydrocarbons (PAHs).
  • Main Results:

    • Distinct emission periods observed: H₂S (0-150 min), VOCs (0-270 min).
    • Polycyclic aromatic hydrocarbons (PAHs) were primary contributors to OFP (approx. 65%) and SOAFP (25%-60%).
    • Emission sources transition from rubber to petroleum asphalt with increasing thermal exposure.

    Conclusions:

    • Crumb rubber size and thermal duration significantly impact VOC emissions and environmental burdens.
    • PAHs and high molecular weight aliphatic hydrocarbons (ALHs) are key contributors to OFP and SOAFP.
    • Targeted emission suppression strategies are necessary for sustainable RMA applications.