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Updated: Jun 18, 2025

Measurement of Ultrafast Vibrational Coherences in Polyatomic Radical Cations with Strong-Field Adiabatic Ionization
Published on: August 6, 2018
Gas-phase vibrational spectroscopy of the dysprosium monoxide molecule and its cation
Sascha Schaller1, Sandy Gewinner1, Wieland Schöllkopf1
1Fritz-Haber-Institut der Max-Planck-Gesellschaft, Faradayweg 4-6, 14195 Berlin, Germany. fielicke@fhi-berlin.mpg.de.
Abstract:
Rotationally resolved vibrational spectra of DyO and DyO+ in a molecular beam are obtained by IR excitation from the X8 ground state and from high-n Rydberg states of DyO using an infrared free electron laser. Vibrational excitation is detected either by resonance enhanced multiphoton ionisation from X8(v = 1) or by autoionisation of Rydberg states converging to DyO+(v = 1). For most heavy molecules, the large spectral width of an infrared free electron laser does not allow for rotational resolution. In DyO and DyO+ the P, Q, and R transitions can be resolved due to the high angular momentum in their ground states. For 164DyO a vibrational constant of ωe = 847.5(2) cm-1 and a vibrational anharmonicity of ωeχe = 2.9(1) cm-1 are deduced. For the 161DyO+ cation a transition frequency of ΔG1/2 = 907(1) cm-1 is found.
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