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Complexing agent-assisted Cr(VI) removal in a continuous fixed-bed system with nanoscale Fe0/NaA molecular sieve
Jian Liu1, Xueren Huang2, Zhengji Yi1
1College of Chemistry and Materials Science, Hengyang Normal University, Hengyang, 421008, China; Key Laboratory of Functional Metal-Organic Compounds of Hunan Province, Hengyang, 421008, China; Hunan Engineering Research Center for Monitoring and Treatment of Heavy Metals Pollution in the Upper Reaches of Xiangjiang River, Hengyang, 421008, China.
Abstract:
Complexing agents (CAs) can be used for the removal of Cr(VI) via nanoscale Fe0 (nZVI) reduction in cost-effective manner. However, nZVI is prone to aggregation and passivation, and some conventional CAs are toxic and difficult to biodegrade, potentially causing secondary pollution. Therefore, selecting an environmentally friendly CA for assisting in the removal of Cr(VI) via supported nZVI is imperative. Herein, NaA molecular sieve membrane-supported nZVI (nZVI/NaA-NF) was prepared via the secondary growth and liquid-phase reduction method using nickel foam (NF) as the carrier. The physicochemical characteristics of nZVI/NaA-NF before and after reaction were analysed via SEM, EDS, and XPS. A CA-improved nZVI/NaA-NF was used for the effective removal of Cr(VI) in a continuous fixed-bed system. Furthermore, the influences of various experimental factors including the CA type, CA concentration, solution pH, space velocity, and inlet Cr(VI) concentration on Cr(VI) removal were systematically investigated. The results demonstrated that nZVI particles were homogeneously immobilized on the NaA molecular sieve membrane/NF for fresh nZVI/NaA-NF, and tetrasodium iminidisuccinate (IDS-4Na) inhibited the aggregation of Cr(III)/Fe(III) (hydr)oxide precipitates during the reaction. IDS-4Na demonstrated excellent promotive effect on Cr(VI) removal via nZVI/NaA-NF. The breakthrough time for Cr(VI) in the addition of IDS-4Na was considerably longer than that of nZVI/NaA-NF alone. The breakthrough concentration of Cr(VI) only reached 1.1% and 9.9% of the inlet concentration at 220 and 240 min, with an IDS-4Na concentration of 4 mM, a pH of 2.5, and a space velocity of 0.265 min-1. The Bohart-Adams model was appropriate to predict the initial part of Cr(VI) breakthrough curves in the nZVI/NaA-NF fixed bed. The saturated concentration (N0) increased with an increase in inlet Cr(VI) concentration. The Yoon-Nelson model afforded good fitting results for all breakthrough curves of Cr(VI). The k' value increased with an increase in space velocity, and the τ value decreased.
