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Updated: Jun 18, 2025

Hydrogen Production and Utilization in a Membrane Reactor
Published on: March 10, 2023
Voltammetric determination of hydrogen peroxide at decorated palladium nanoparticles/poly 1,5-diaminonaphthalene
Ziad Khalifa1, Mohamed Fathi Abo Oura2, Abla Hathoot2
1Chemical Engineering Department, Faculty of Engineering, The British University in Egypt, El Sherouk City 11837, Egypt.
Abstract:
In this work, palladium nanoparticles (PdNPs)/p1,5-DAN/ carbon paste electrode (CPE) and p1,5-DAN/CPE sensors have been developed for determination of hydrogen peroxide. Both sensors showed a highly sensitive and selective electrochemical behaviour, which were derived from a large specific area of poly 1,5 DAN and super excellent electroconductibility of PdNPs. PdNPs/p1,5-DAN/CPE exhibited excellent performance over p1,5-DAN/CPE. Thus, it was used for detecting hydrogen peroxide (H2O2) with linear ranges of 0.1 to 250 µM and 0.2 to 300 µM as well as detection limits (S/N = 3) of 1.0 and 5.0 nM for square wave voltammetry (SWV) and cyclic voltammetry (C.V) techniques, respectively. The modified CPE has good reproducibility, adequate catalytic activity, simple synthesis and stability of peak response during H2O2 oxidation on long run that exceeds many probes. Both reproducibility and stability for H2O2 detection are attributable to the PdNPs immobilized on the surface of p1,5-DAN/CPE. The modified CPE was used for determining H2O2 in real specimens with good stability, sensitivity, and reproducibility.
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