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Updated: Jun 18, 2025

Synthesis of Bimetallic Pt/Sn-based Nanoparticles in Ionic Liquids
Published on: August 23, 2018
A twist on a classic scaffold: rational design of a new bimetallic platform
Sultana P Rumi1, Lev N Zakharov1, Addison N Desnoyer1
1Department of Chemistry, Oregon State University, Corvallis, OR, 97331, USA. addison.desnoyer@oregonstate.edu.
Abstract:
Herein, we report the synthesis of a modular family of novel bimetallic tetraamidodiamine (tada) ligands, Li4-R-tada (R = Me3Si, BuMe2Si, and iPr3Si). These silylamido ligands display two distinct binding pockets whose steric profiles can be easily tuned by choice of the substituents on silicon. We also show that salt metathesis is a convenient route to install these new ligands on the early transition metals titanium(IV) and vanadium(III).
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