Pair correlations of the easy magnetisation axes of superparamagnetic nanoparticles in a ferrofluid/ferrocomposite

The widespread use of magnetic nanoparticles in modern technologies and medical applications highlights the need for reliable theoretical models that can predict their physical properties. The pair correlation function of two randomly selected superparamagnetic nanoparticles in a ferrofluid/ferrocomposite is studied to depict the joint probability density of the easy magnetisation axes across the planes of parameters of major importance; these are the interaction of ferroparticles with an external magnetic field, the energy of magnetic anisotropy inside the superparamagnetic nanoparticle, and the interparticle magnetic dipole-dipole interaction. Assuming the rotational symmetry of the system, we come to the conclusion that the pair correlations of interest are dependent only on the polar angles, determining the inclinations of the ferroparticle easy axes from the direction of an external magnetic field. The dimer configuration, where two ferroparticles are in close contact along a magnetic field with their easy magnetisation axes aligned, is the most probable. This configuration becomes more pronounced with increasing anisotropy energy, dipolar coupling constant, and external magnetic field.