Climate change accelerates water and biogeochemical cycles in temperate agricultural catchments

Climate change is expected to significantly deteriorate water quality in heavily managed agricultural landscapes, however, the exact mechanisms of these impacts are unknown. In this study we adopted a modelling approach to predict the multiple effects of climate change on hydrological and biogeochemical responses for dominant solutes and particulates in two agriculture-dominated temperate headwater catchments. We used climatic projections from three climatic models to simulate future flows, mobilisation and delivery of solutes and particulates. This allowed an examination of potential drivers by identifying changes in flow pathway distribution and key environmental variables. We found that future climate conditions will lead to a general increase in stream discharge as well as higher concentrations and loads of solutes and particulates. However, unlike previous studies, we observed a higher magnitude of change during the warmer part of the year. These changes will reduce the relative importance of winter flows on solute and particulate transport, leading to both higher and more evenly distributed concentrations and loads between seasons. We linked these changes to the higher importance of superficial flow pathways of tile and surface runoff driven by more rapid transition from extremely wet to dry conditions. Overall, the observed increase in solute and particulate mobilisation and delivery will lead to widespread water quality deterioration. Mitigation of this deterioration would require adequate management efforts to address the direct and indirect negative effects on stream biota and water scarcity.