Heterointerface engineering of MXene: Advanced applications in environmental remediation

Contemporary global industrialization, coupled with the relentless growth of the population, has led to a persistent escalation in the emission and accumulation of various toxic and harmful chemicals in the environment, severely disrupting the ecological balance. The development of efficient environmental cleanup materials is a crucial scientific and technological concern. Since the groundbreaking work on Ti₃C₂T_x in 2011, there has been a huge growing interest in MXene-based composites developed through heterointerface engineering due to its high surface area, hydrophilicity, eco-friendliness, biocompatibility, easy functionalization, excellent thermal/mechanical properties, metal conductivity and rich electronic density. In the area of environmental remediation, MXene-based composites obtained through heterointerface engineering strategies have the ability to effectively remove and systematically monitor contaminants in comparison to virgin MXene, thanks to the synergistic effects and complementary benefits. Heterointerface engineering strategy increases specific surface area, introduces catalytic sites, constructs heterojunctions/Schottky junctions, and facilitates carrier migration and electron-hole separation. These novel MXene-based composites represent significant advances in MXene research and deserve a comprehensive review. Although several excellent reviews and perspectives on the application of MXene-based composites in environmental remediation have been published, there is still a scarcity of comprehensive and systematic assessments on the reliable data and mechanisms of various MXene-based composite materials for pollutant removal and monitoring. In this focused review, the first part briefly introduces the common preparation strategies and characterization methods of single MXene and MXene-based composites, and the second part details the innovative application of MXene-based composites (involving the amalgamation of MXene with metal oxides, metal sulfide, g-C₃N₄, layered double hydroxides, metal-organic frameworks, single atom/quantum dots, polymers, etc.) in the field of environmental remediation, including carbon dioxide reduction, nitrogen monoxide and volatile organic compounds removal, antibiotic and heavy metal ions degradation, summarizing the relevant performance and mechanisms. Furthermore, the recent advancements in the utilization of MXene-based composites for the sensing of emerging environmental contaminants (antibiotic and antibiotic resistance genes) are summarized. Finally, an outline of the existing challenges and future prospects on this exciting field was narrated for plausible real-world use. This review will help to inspire the diverse design of MXene-based composites and to advance research related to their application in the environmental sector.