Investigation of Thermal and Spectroscopic Properties of Tellurite-Based Glasses Doped with Rare-Earth Oxides for...

The thermal and optical properties of 60TeO₂-20K₂TeO₃-10WO₃-10Nb₂O₅ (in mol%) glasses doped with Ho₂O₃, Er₂O₃, and Tm₂O₃ were explored in the present work. The thermal stability, refractive index n, extinction coefficient k, absorption coefficient α, and optical band gap of the glasses were evaluated. The UV-Vis-NIR absorption spectra, the Judd-Ofelt intensity parameter, the spectroscopic quality factor, and the emission and absorption cross-sections were calculated to investigate the effects of Er³⁺ and Tm³⁺, respectively, on the band spectroscopic properties of Ho³⁺ ions. The results showed that the maximum emission cross-section was approximately 8×10-21 cm2, and the values of the full width at half maximum (FWHM), quality factor (σe×FWHM), and gain coefficient of Ho³⁺: ⁵I₇→⁵I₈ were also reported. The value of the FWHM×σe was 1200×10-28 cm3, which showed greater gain characteristics than earlier study results. For 2 μm mid-infrared solid-state lasers, the glasses that were examined might be a good host material.