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Preparation and Reactivity of Gasless Nanostructured Energetic Materials
Published on: April 2, 2015
2,2'-Bisdinitromethyl-5,5'-bistetrazole: A High-Performance, Multi-Nitro Energetic Material with Excellent Oxygen
Yiling Yang1, Wenjin Zhang1, Siping Pang1
1School of Materials Science & Engineering, Beijing Institute of Technology, Beijing 100081, China.
Abstract:
Bistetrazoles are highly sought after for developing innovative high-energy density materials. The 1,1'-substituted bistetrazoles, exemplified by TKX-50, have outstanding performance. However, the research of high-perfomance 2,2'-substituted bistetrazoles remains limited. In this work, dinitromethyl groups were introduced into bistetrazole structures as 2,2'-substituted bistetrazoles (BDBTZ), which was extensively characterized through NMR, thermal analysis, and single crystal X-ray diffraction, exhibiting excellent oxygen balance, moderate sensitivity, acceptable thermal stability, high crystal density, and excellent detonation performance.
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