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Analysis of Macronutrients in Soil Using Impedimetric Multisensor Arrays
Maria Luisa Braunger1, Mario Popolin Neto2, Dmitry Kirsanov3,4
1Instituto de Física "Gleb Wataghin" (IFGW), Universidade Estadual de Campinas-UNICAMP, Campinas 13083-859, São Paulo, Brazil.
ACS Omega
|August 12, 2024
Summary
Precision agriculture uses sensors for site-specific fertilization to boost crop yield. This study developed an impedimetric multisensor array for soil nutrient analysis, improving efficiency and environmental sustainability in farming.
Area of Science:
- Agricultural Science
- Sensor Technology
- Environmental Science
Background:
- Global population growth necessitates increased food production.
- Precision agriculture offers strategies to enhance crop yield sustainably.
- Site-specific fertilization requires accurate soil nutrient monitoring.
Purpose of the Study:
- To develop and compare impedimetric multisensor arrays for soil nutrient analysis (N, P, K).
- To evaluate the effectiveness of ion-selective membranes versus layer-by-layer films in sensor arrays.
- To apply multidimensional projection and machine learning for sensor calibration and data analysis.
Main Methods:
- Development of two impedimetric multisensor arrays: one with ion-selective membranes and another with layer-by-layer films.
- Analysis of soil samples enriched with macronutrients (N, P, K).
- Application of multidimensional projection techniques and machine learning (decision tree algorithm) for calibration.
Main Results:
- Both sensor arrays effectively distinguished soil samples.
- The ion-selective membrane array demonstrated higher sensitivity to potassium (K) content.
- Machine learning algorithms optimized sensor calibration by selecting best frequencies and sensors.
Conclusions:
- Impedimetric multisensor arrays are viable tools for precise soil nutrient analysis.
- Ion-selective membranes offer enhanced sensitivity for specific nutrient detection, particularly potassium.
- These advancements support environmentally friendly agriculture through optimized fertilizer application and improved crop yields.

