Related Experiment Video
Updated: Jun 16, 2025

Synthesis of Metal Nanoparticles Supported on Carbon Nanotube with Doped Co and N Atoms and its Catalytic Applications in Hydrogen Production
Published on: December 6, 2021
Strong metal-support interaction (SMSI) in environmental catalysis: Mechanisms, application, regulation strategies,
Fuyuan Qi1, Jianfei Peng1, Zilu Liang1
1Tianjin Key Laboratory of Urban Transport Emission Research & State Environmental Protection Key Laboratory of Urban Ambient Air Particulate Matter Pollution Prevention and Control, College of Environmental Science and Engineering, Nankai University, Tianjin, 300071, China.
Abstract:
The strong metal-support interaction (SMSI) in supported catalysts plays a dominant role in catalytic degradation, upgrading, and remanufacturing of environmental pollutants. Previous studies have shown that SMSI is crucial in supported catalysts' activity and stability. However, for redox reactions catalyzed in environmental catalysis, the enhancement mechanism of SMSI-induced oxygen vacancy and electron transfer needs to be clarified. Additionally, the precise control of SMSI interface sites remains to be fully understood. Here we provide a systematic review of SMSI's catalytic mechanisms and control strategies in purifying gaseous pollutants, treating organic wastewater, and valorizing biomass solid waste. We explore the adsorption and activation mechanisms of SMSI in redox reactions by examining interfacial electron transfer, interfacial oxygen vacancy, and interfacial acidic sites. Furthermore, we develop a precise regulation strategy of SMSI from systematical perspectives of interface effect, crystal facet effect, size effect, guest ion doping, and modification effect. Importantly, we point out the drawbacks and breakthrough directions for SMSI regulation in environmental catalysis, including partial encapsulation strategy, size optimization strategy, interface oxygen vacancy strategy, and multi-component strategy. This review article provides the potential applications of SMSI and offers guidance for its controlled regulation in environmental catalysis.
More Related Videos
10:57Synthesis and Performance Characterizations of Transition Metal Single Atom Catalyst for Electrochemical CO2 Reduction
Published on: April 10, 2018
12:08Catalytic Reactions at Amine-Stabilized and Ligand-Free Platinum Nanoparticles Supported on Titania During Hydrogenation of Alkenes and Aldehydes
Published on: June 24, 2022
Related Concept Videos
Introduction to Mechanisms of Enzyme Catalysis
Catalysis
Metal-Ligand Bonds
In these complexes, transition metals form coordinate covalent bonds, a kind of Lewis acid-base interaction in which both of the electrons in the bond are contributed by a donor (Lewis base) to an electron acceptor (Lewis acid). The Lewis acid in...
Complexation Equilibria: Factors Influencing Stability of Complexes
Reduction of Alkenes: Asymmetric Catalytic Hydrogenation
The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...
Factors Influencing the Rate of Chemical Reactions
Concentration and Pressure:
The more particles present within a given space, the more likely those particles are to bump into one another....