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Updated: Jun 16, 2025
Fabrication Procedures and Birefringence Measurements for Designing Magnetically Responsive Lanthanide Ion Chelating Phospholipid Assemblies
Published on: January 3, 2018
Single-Molecule Magnet Rods: Remarkably Elongated Lanthanide Phosphonate Cores with Quasilinear Hydrazones
XiaoJuan Li1, Xiao Sun1, Chaolun Wei1
1Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, School of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng 252059, P. R. China.
Abstract:
Large metal-phosphonate clusters typically exhibit regular polyhedral, wheel-shaped, spherical, or capsule-shaped morphologies more effectively than high-aspect ratio topologies. A system of elongated lanthanide core topologies has now been synthesized by the reaction of lanthanide 1-naphthylmethylphosphonates and four differently terminated pyrazinyl hydrazones. Four new rod-shaped dysprosium phosphonate clusters, [Dy6(O3PC11H9)4(L1)4(μ4-O)(DMF)4]·2DMF·3MeCN·3H2O (1), [Dy8(O3PC11H9)4(L2)4(μ3-O)4(CO2)4(H2O)4]·6DMF·4MeCN·3H2O (2), [Dy12Na(O3PC11H9)6(L3)6(μ3-O)2(pyr)6]·DMF·2MeCN·H2O (3), and [Dy14(O3PC11H9)12(L4)8(μ3-O)2(DMF)4(MeOH)2(H2O)4]·5DMF·2MeCN·H2O (4), were obtained. Four single-pyrazinyl hydrazones function as pentadentate bis-chelate terminal co-ligands, coordinating the periphery of dysprosium phosphonate rods. A sodium ion serves as a cation template for constructing heterobimetallic 3 by occupying the void, demonstrating the ability to reliably control cluster length by modifying the hydrazone co-ligand structure and cation template. Additionally, it was observed that the elongation of the rods has a significant directional impact on the magnetic relaxation behavior, transitioning from a one-step process in 1 to a three-step process in 2, a two-step process in 3, and finally a two-step process in 4.
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