Related Experiment Video
Updated: Jun 16, 2025

Author Spotlight: Magnetometric Characterization of Intermediates in the Solid-State Electrochemistry of Redox-Active Metal-Organic Frameworks
Published on: June 9, 2023
Dimensionality-Tailored Ferromagnetism in Quasi-Two-Dimensional MnSe2 for the Magnetoelectrochemical Hydrogen
Krishnendu Roy1, Raktim Datta1, Soumyajit Maitra1
1School of Materials Sciences, Indian Association for the Cultivation of Science, Kolkata700032, India.
Abstract:
The application of an external magnetic field to the cathode shows great promise in facilitating the hydrogen evolution reaction (HER) via water electrolysis. However, the criteria for designing such cathodes are still under investigation. Among various aspects, understanding the effect of different magnetic states of the cathode material is crucial, especially for the HER in alkaline conditions, which possesses different reaction steps compared to that in acidic conditions. Herein, we present MnSe2 as a cathode material for the magneto-electrocatalytic HER in alkaline media, utilizing its dimension-dependent magnetic phase transition. By tailoring its dimensionality, we have achieved room-temperature ferromagnetism in its quasi-two-dimensional (2D) form, whereas its bulk counterpart exhibits paramagnetism. Upon being subjected to a low external magnetic field of 0.4 T at -182 mV (vs RHE) overpotential, quasi-2D MnSe2 exhibited a 120% improvement in current density compared to itself at zero magnetic field, while negligible changes were observed in the bulk material. This performance enhancement under a magnetic field could originate from the higher spin polarization of the ferromagnetic catalyst. This work signifies a conceptual advancement of the catalyst's spin state in magnetically enhanced electrocatalytic reaction kinetics.
More Related Videos
Related Concept Videos
Ferromagnetism
Paramagnetism
π Electron Effects on Chemical Shift: Overview
Diamagnetism
Diamagnetism was discovered by Anton Brugmans in 1778 when he observed that bismuth gets repelled by magnetic fields, thus theorizing that diamagnets get repelled by magnets....
Colors and Magnetism
When atoms or molecules absorb light at the proper frequency, their electrons are excited to higher-energy orbitals. For many main group atoms and molecules, the absorbed photons are in the ultraviolet range of the electromagnetic spectrum, which cannot be detected by the human eye. For coordination compounds, the energy difference between the d orbitals often allows photons in the visible range to be absorbed and emitted, which is seen as colors by the human...
Magnetic Moment of an Electron

