Functionalized chitosan-inspired (nano)materials containing sulfonic acid groups: Synthesis and application

Nature-inspired chitosan (CS) materials show a high potential for the design/fabrication of sustainable heterogeneous (nano)materials with extraordinary structural/physical features, such as superior biodegradability/biocompatibility, simplicity of chemical modification, environmental safety, high availability, cost-effectiveness, high electrochemical activity, good film-forming ability, and antioxidant, antimicrobial/antibacterial, and anticoagulant activities. Industrialization and growth of industrial wastes or by-products induce an increasing demand for the development of clean, low-cost, and renewable natural systems to minimize or eliminate the utilization of environmentally toxic compounds. The preparation of novel heterogeneous functionalized polysaccharide-inspired bio(nano)materials via chemical modifications of natural CS to improve its physicochemical/biochemical properties has recently become tremendously attractive for many researchers. The most abundantly available and cost-effective functionalized CS-inspired (nano)materials are considerably valuable in terms of the economic aspects of production of (nano)catalysts, (nano)hydrogels, (nano)composite/blend membranes, and thus their commercialization. In this respect, the preparation of functionalized CS-inspired (nano)materials containing -SO₃H groups has been represented as a valid alternative to the homogenous unmodified biomaterials for various applications. Sulfonated derivatives of CS-inspired (nano)materials may possess huge surface areas, catalytic activity, adsorption, and biological/biomedical properties. This review article is aimed at the investigation of different methods and potential applications of sulfonated CS-inspired (nano)materials in catalysis, fuel cells, adsorption of ions, membranes, and biological applications.