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Porosity in Cement Paste01:18

Porosity in Cement Paste

119
The porosity of concrete is a measure of the void spaces within its structure. These spaces impact its strength and durability significantly. When water and cement interact, a chemical reaction called hydration creates a semi-solid paste. This paste includes combined water, making up approximately 23% of the cement's dry mass, and gel water, which fills minuscule voids known as gel pores, accounting for about 28% of the cement gel volume.
The balance of water to cement in the mix is...
119
Pore Transport and Ion-Pair Transport01:17

Pore Transport and Ion-Pair Transport

399
Pore transport and ion-pair formation are critical mechanisms for the absorption and distribution of drugs in the body.
Pore transport, also known as convective transport, is a process where small molecules like urea, water, and sugars rapidly cross cell membranes as though there were channels or pores in the membrane. Although direct microscopic evidence is limited  but the concept of pores or channels is widely accepted based on physiological evidence. Despite the lack of direct...
399
Porosity and Absorption of Aggregate01:20

Porosity and Absorption of Aggregate

271
Aggregates contain pores of varying sizes; while some are completely enclosed within the particles, others open onto the surface, allowing water to penetrate. The porosity of aggregates is a major factor contributing to the overall porosity of concrete, given that aggregates constitute about three-quarters of concrete's volume.
When all pores in an aggregate are filled with water, the aggregate is considered saturated and surface-dry. If left in dry air, water will evaporate until the...
271
Pozzolans01:21

Pozzolans

106
Pozzolans are siliceous or aluminous materials blended with Portland cement. They interact with the calcium hydroxide produced during the hydration of Portland cement and contribute to improved strength and durability of concrete. The pozzolanic activity, a measure of a pozzolan's effectiveness, is typically assessed using the strength activity index, as defined in ASTM C 618-93, which calculates the ratio of the compressive strength of cement mixtures with and without pozzolan.
Fly ash is...
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Related Experiment Video

Updated: Jun 15, 2025

Author Spotlight: Characterizing Porous Materials for Aiding the Development of Robust Metal-Organic Frameworks with Adsorption Behavior
06:45

Author Spotlight: Characterizing Porous Materials for Aiding the Development of Robust Metal-Organic Frameworks with Adsorption Behavior

Published on: March 8, 2024

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Emerging Mixed-Valence Porous Materials.

Watchareeya Kaveevivitchai1, Teng-Hao Chen2

  • 1Department of Chemical Engineering, Hierarchical Green-Energy Materials (Hi-GEM) Research Center, Academy of Innovative Semiconductor and Sustainable Manufacturing, National Cheng Kung University, Tainan City, 70101, Taiwan.

Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry
|August 27, 2024
PubMed
Summary
This summary is machine-generated.

Researchers are exploring mixed valency in crystalline porous materials like metal-organic frameworks to enhance properties. This strategy is key for developing advanced materials with tailored charge-transport, magnetic, and catalytic functions.

Keywords:
Intervalence charge transferMetal–organic frameworksMixed-valencePorous materialsRedox-non-innocent

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Area of Science:

  • Materials Science
  • Chemistry
  • Nanotechnology

Background:

  • Porous materials have advanced significantly, with applications revolutionized by tailored properties.
  • Incorporating mixed valency is a key strategy to fine-tune material behaviors like charge-transport, magnetism, and catalysis.

Purpose of the Study:

  • To review recent progress in crystalline porous materials with mixed valency.
  • To highlight the investigation and potential applications of these advanced materials.

Main Methods:

  • Focuses on crystalline porous materials including metal-organic frameworks, metal-organic polyhedra, covalent organic frameworks, and hydrogen-bonded organic frameworks.
  • Discusses materials with intrinsic mixed valency and those modified postsynthetically via external stimuli.

Main Results:

  • Mixed valency can be intrinsic or induced, offering versatile control over material properties.
  • Emerging crystalline porous materials demonstrate significant potential in various applications.

Conclusions:

  • Mixed-valence crystalline porous materials offer exciting opportunities for designing advanced functional materials.
  • Further investigation into mixed valency is crucial for exploiting the full potential of these materials.