Emerging Mixed-Valence Porous Materials

The development and applications of porous materials have been revolutionized over the past decades. To fine-tune their fascinating behaviors such as charge-transport, magnetic, and catalytic properties, one of the most effective strategies is incorporating mixed valency into the structures. This Concept provides recent progress on emerging crystalline porous materials, namely, metal-organic frameworks, metal-organic polyhedra, covalent organic frameworks, and hydrogen-bonded organic frameworks, where their mixed valency is either intrinsic or postsynthetically induced via an external stimulus. We further highlight the investigation of mixed valency and potential applications, which sheds light on the design and exploitation of mixed-valence crystalline porous materials.