Urea-driven g-C₃N₄ nanostructures for highly efficient photoreduction of Cr(vi) under visible LED light: effects of...

Graphitic carbon nitride (g-C₃N₄) nanostructures were synthesized via the calcination of urea at various temperatures ranging between 400 and 600 °C and were utilized for photoreduction of Cr(vi) in aqueous medium. Due to the low adsorption of Cr(vi) on the g-C₃N₄ surface, a more accurate assessment of the photocatalytic performance of the samples was carried out. Although the characterization showed that the specific surface of samples increased as the calcination temperature increased, the most efficient product in terms of the photoreduction duration of Cr(vi) was produced through the calcination process carried out at 450 °C, which reduced the concentration by more than 99% in 40 minutes. These results demonstrate that the structural and surface properties of g-C₃N₄ are critical factors that impact the photocatalytic performance. Alongside the calcination temperatures, the concentration of citric acid as a hole scavenger, the source of illumination, pH levels, and the recycling ability of the produced specimen at 450 °C were also investigated. Conspicuously, the photocatalyst works better when more citric acid is present and the pH level decreases. Out of all the cases studied regarding the light source, the 400 nm LED light source was found to be the most efficient. Additionally, even after going through the photoreduction process four times, the photocatalyst still remained highly efficient.