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Updated: Jun 15, 2025

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Fabrication, Densification, and Replica Molding of 3D Carbon Nanotube Microstructures
Published on: July 2, 2012
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Buckypaper made with carbon nanotubes derived from CO2
Gad Licht1, Kyle Hofstetter2, Stuart Licht1,2,3
1Direct Air Capture LLC, A4 188 Triple Diamond Blvd North Venice FL 34275 USA slicht@gwu.edu.
RSC Advances
|August 28, 2024
Summary
Researchers created novel graphene nanocarbon (GNC) buckypapers directly from carbon dioxide (CO2) using molten carbonate electrolysis. This innovative method offers a sustainable pathway for producing advanced carbon materials from a greenhouse gas.
Area of Science:
- Materials Science
- Nanotechnology
- Electrochemistry
Background:
- Graphene nanocarbons (GNCs), including carbon nanotubes (CNTs), are advanced materials with diverse applications.
- Sustainable production of GNCs is crucial for environmental and economic reasons.
- Carbon dioxide (CO2) is a readily available greenhouse gas that can serve as a carbon source.
Purpose of the Study:
- To develop a novel method for synthesizing GNCs directly from CO2.
- To fabricate unusual buckypapers using GNCs derived from CO2.
- To explore different processing techniques for GNCs obtained via molten carbonate electrolysis.
Main Methods:
- Molten carbonate electrolysis was employed to derive GNCs directly from CO2.
- GNCs were processed using methods such as crushing, chemical washing, and hot electrolyte pressing.
- Epoxy-infused CNTs were also prepared and characterized.
Main Results:
- Successful formation of buckypapers (sheets of GNCs) directly from CO2.
- Demonstration of various GNC processing techniques yielding different buckypaper characteristics.
- Characterization of GNCs derived from CO2, showcasing their potential for material fabrication.
Conclusions:
- Direct conversion of CO2 into GNCs via molten carbonate electrolysis is feasible.
- This method provides a sustainable route for producing graphene nanocarbon materials.
- The developed buckypapers show promise for various advanced material applications.

