Migration of depleted uranium from a corroded penetrator in soil vadose zone in Bosnia and Herzegovina
- Cui Li 1, Yanru Liang 1, Yin Ye 1, Fan Chen 1, Markus Astner 2, David J Paterson 3, Yanlong Chen 1, Linlin Wang 1, Paul Guagliardo 4, Matvei Aleshin 4, Mario Burger 2, Peter M Kopittke 5, Yuheng Wang 1
- Cui Li 1, Yanru Liang 1, Yin Ye 1
- 1Northwestern Polytechnical University, School of Ecology and Environment, Xi'an 710129, China; Northwestern Polytechnical University, Shaanxi Key Laboratory of Qinling Ecological Intelligent Monitoring and Protection, Xi'an 710129, Shaanxi, China.
- 2Federal Office for Civil Protection, Spiez Laboratory, Physics Division, CH-3700 Spiez, Switzerland.
- 3ANSTO, Australian Synchrotron, Clayton, Victoria 3168, Australia.
- 4University of Western Australia, Centre for Microscopy, Characterisation and Analysis, Perth, WA 6009, Australia.
- 5The University of Queensland, School of Agriculture and Food Sustainability, St Lucia, Queensland 4072, Australia.
- 0Northwestern Polytechnical University, School of Ecology and Environment, Xi'an 710129, China; Northwestern Polytechnical University, Shaanxi Key Laboratory of Qinling Ecological Intelligent Monitoring and Protection, Xi'an 710129, Shaanxi, China.
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View abstract on PubMed
Summary
This summary is machine-generated.Depleted uranium (DU) from corroded armor penetrators shows slow downward soil migration over 7 years. Long-term corrosion poses a significant environmental risk, necessitating remediation strategies for contaminated sites.
Area Of Science
- Environmental Science
- Geochemistry
- Soil Science
Background
- Depleted uranium (DU) penetrators from conflicts contaminate soil and pose risks to groundwater.
- Studies on DU migration in former war zones are limited.
- Corrosion of DU armor penetrators over time leads to environmental contamination.
Purpose Of The Study
- To investigate the vertical migration of DU in a soil profile.
- To determine the extent and rate of DU contamination from a corroded penetrator.
- To understand the chemical forms and mechanisms of DU migration in soil.
Main Methods
- Analysis of DU concentration in soil samples at varying depths.
- Identification of uranium-bearing particles and mineral phases using microscopy and spectroscopy.
- X-ray absorption spectroscopy (XAS) to determine the oxidation state of uranium.
Main Results
- Highest DU concentration (∼45,300 mg/kg) found at 6-10 cm depth, decreasing with depth.
- DU migration front reached approximately 42 cm beneath a 7-year-corroded penetrator.
- Uranium was primarily hexavalent, found adsorbed on clay minerals and iron oxides, with metaschoepite identified.
Conclusions
- DU migration in the vadose zone is relatively slow but poses a long-term environmental risk.
- Effective remediation strategies are crucial to mitigate DU contamination from legacy penetrators.
- Understanding DU migration dynamics is essential for safeguarding ecosystems and human health.
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