Swiss roll nanoarrays for chiral plasmonic photocatalysis

Manipulating the chirality at nanoscale has drawn great attention among scientists, considering its pivotal role in various applications of current interest, including nano-optics, biomedicine, and photocatalysis. In this work, we delve into this arena by fabricating chiral Swiss roll nanoarray (SRNA) continuous films employing colloidal lithography. The technique permits the dimension of Swiss roll metamaterials to reduce to nanoscale, thus achieving chiroptical response (circular dichroism (CD)) in the visible region. The interplay between the CD signals and plasmon resonance modes is revealed through theoretical simulations, enabling a deep understanding of chiral plasmonic metamaterials. The polarization-sensitive photocatalytic activity of chiral SRNAs is investigated, noting a marked increase in the reaction rate when the chirality of SRNAs matches with the handedness of circularly polarized light (CPL). Notably, the SRNA continuous films based on substrate possess integration and reusability without complex recycling process, enhancing their practicality in applications like sensing and plasmonic nanochemistry, particularly toward polarization-dependent photocatalysis.