Long-Cycling Cellulose-Based Gel Polymer Electrolyte Utilizing Nanohydrotalcite as a Li⁺ Transport Redistributor

The hydroxyl groups on the surface of the cellulose-based gel polymer electrolyte lead to poor interfacial compatibility due to side reactions with lithium sheets. In this paper, a novel cellulose-based gel polymer electrolyte was prepared by uniformly coating the surface of a cellulose membrane with a nanohydrotalcite/PVDF-HFP composite using electrospinning technology. This cellulose-based gel polymer electrolyte exhibits good interfacial compatibility and excellent cycling stability (91.7% specific capacity retention after 500 cycles at 0.5C). Theory and experiments have shown that nanohydrotalcite on the surface of cellulose membrane can effectively prevent the contact of hydroxyl groups with lithium sheets to reduce the side reactions. In addition, nanohydrotalcite can also act as a Li⁺ transport redistributor to facilitate the uniform deposition of Li⁺ and reduce the formation of lithium dendrites to extend the cycle life.