Related Experiment Video
Updated: Jun 14, 2025

Preparation of a Corannulene-functionalized Hexahelicene by CopperI-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units
Published on: September 18, 2016
Chemical mechanisms of hexachlorobutadiene reactions in the environment
1State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing, 100085, China; School of Environment, Hangzhou Institute for Advanced Study, UCAS, Hangzhou, 310024, China; College of Resource and Environment, University of Chinese Academy of Sciences, Beijing, 100049, China.
Abstract:
Hexachloro-1,3-butadiene (HCBD) has received increasing attention because of its adverse effects on human health. Although HCBD is regulated under the Stockholm Convention, it is still widely detected in the environment. However, detailed reports on the chemical mechanisms of HCBD reactions in the environment are lacking. This review comprehensively summarizes HCBD's unintentional industrial sources and formation mechanisms, and chemical reactions and transformations in different media (gas, water, and biological phases). Photochemical reactions in the atmosphere can degrade and transform HCBD and potentially form other toxic compounds, such as phosgene. Aerobic pyrolysis of HCBD can generate complex byproducts. Further research is essential to fully understand the environmental behavior of HCBD.
More Related Videos
05:34Efficient Synthesis of Polyfunctionalized Benzenes in Water via Persulfate-promoted Benzannulation of α,β-Unsaturated Compounds and Alkynes
Published on: December 16, 2019
06:46Facile Preparation of 2Z,4E-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate
Published on: June 21, 2017
Related Concept Videos
Electrophilic 1,2- and 1,4-Addition of HX to 1,3-Butadiene
Electrophilic Addition of HX to 1,3-Butadiene: Thermodynamic vs Kinetic Control
Electrophilic 1,2- and 1,4-Addition of X2 to 1,3-Butadiene
Radical Substitution: Hydrogenolysis of Alkyl Halides with Tributyltin Hydride
The bonds formed in this reaction are stronger than the bonds broken, making it energetically favorable. The reaction follows a radical chain mechanism similar to radical halogenation...
Reduction of Benzene to Cyclohexane: Catalytic Hydrogenation
Radical Anti-Markovnikov Addition to Alkenes: Mechanism
The mechanism starts with chain initiation, which involves two steps. In the first chain initiation step, a weak peroxide bond is homolytically cleaved upon mild heating to form two alkoxy radicals. In the second initiation step, a hydrogen atom is abstracted by the alkoxy...