Adsorption of per- and polyfluoroalkyl substances on biochar derived from municipal sewage sludge

Granular activated carbon (GAC) and ion exchange resin (IXR) are widely used as adsorbents to remove PFAS from drinking water sources and effluent waste streams. However, the high cost associated with GAC and IXR generation has motivated the development of less expensive adsorbents for treatment of PFAS-impacted water. Thus, the objective of this research was to create an economically viable and sustainable PFAS adsorbent from sewage sludge. Stepwise pyrolysis at temperatures from 300 °C to 1000 °C yielded biochars whose specific surface area (SSA) and porosity increased from 41 to 148 m²/g, and from 0.062 to 0.193 cm³/g, respectively. On a per organic char basis, the SSA of the biochar was as high as 1183 m²/g, which is comparable to commercially-available activated carbons. The adsorption of perfluorooctane sulfonic acid (PFOS) on sludge biochar increased with increasing pyrolysis temperature, which was positively correlated with increasing porosity and SSA. When 1000 °C processed biochar was tested with a mixture of eight PFAS, preferential adsorption of longer carbon chain-length species was observed, indicating the importance of PFAS hydrophobic interactions with the biochar and the availability of a wide range of mesopores. The adsorption of each PFAS was dependent upon both chain length and head group, with longer chain-length species exhibiting greater adsorption than shorter chain-length species, along with greater adsorption of species with sulfonic acid head groups compared to their chain length counterparts with carboxylic acid head groups. These findings demonstrate that biochar derived from municipal solid waste can serve as a cost-effective and sustainable adsorbent for the removal of PFOS and PFAS mixtures from source waters. The circular economy benefits and waste reduction potential associated with the use of sewage sludge-derived biochar supports the development of a viable sludge-derived biochar for the removal of PFAS from water.