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Updated: Jun 13, 2025

Measurement of Ultrafast Vibrational Coherences in Polyatomic Radical Cations with Strong-Field Adiabatic Ionization
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Measurement of Ultrafast Vibrational Coherences in Polyatomic Radical Cations with Strong-Field Adiabatic Ionization

Published on: August 6, 2018

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2500 vibronic eigenstates of the NO3 radical

Henrik R Larsson1, Alexandra Viel2

  • 1Department of Chemistry and Biochemistry, University of California, Merced, CA 95343, USA. NO3a[at]larsson-research.δe.

Physical Chemistry Chemical Physics : PCCP
|September 16, 2024
PubMed
Summary

Researchers studied the vibronic structure of the nitrate radical (NO3) using advanced computational methods. They computed over 2500 states, revealing significant discrepancies with experimental data and highlighting the limitations of the Born-Oppenheimer approximation.

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