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Updated: Jun 12, 2025

Preparation and Use of Carbonyl-decorated Carbenes in the Activation of White Phosphorus
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Carbodiphosphorane-Activated Distibene and Dibismuthene Dications

Philipp Dabringhaus1, Andrew Molino1, Robert J Gilliard1

  • 1Department of Chemistry, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, Massachusetts 02139, United States.

Journal of the American Chemical Society
|September 19, 2024
PubMed
Summary

Low-valent antimony and bismuth double bonds exhibit novel reactivity for small molecule activation. Researchers synthesized new distibene and dibismuthene compounds with enhanced accessibility for diverse chemical transformations.

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