Related Experiment Video
Updated: Jun 12, 2025
A Novel Technique for Generating and Observing Chemiluminescence in a Biological Setting
Published on: March 9, 2017
Making soluble Dy2 single-molecule magnets red emissive through their functionalization by ruthenium-cyanido
Michal Liberka1,2, Szymon Chorazy1
1Faculty of Chemistry, Jagiellonian University, Gronostajowa 2, 30-387 Krakow, Poland. simon.chorazy@uj.edu.pl.
Abstract:
We present an efficient strategy for obtaining red-emissive molecular nanomagnets by exploring a heterometallic approach. We report the {[DyIII(4-pyridone)5]2[RuII(CN)2(phen)2]2}·(CF3SO3)6·2MeOH (phen = 1,10-phenanthroline) compound composed of exchange-coupled {DyIII2} single-molecule magnets functionalized by Ru(II)-cyanido units. The latter makes the resulting {DyIII2RuII2}6+ cations a unique example of a soluble lanthanide SMM exhibiting red charge-transfer photoluminescence in the solution and solid state, well enhanced when compared with the cyanido precursor.
More Related Videos
12:07Microwave-assisted Intramolecular Dehydrogenative Diels-Alder Reactions for the Synthesis of Functionalized Naphthalenes/Solvatochromic Dyes
Published on: April 1, 2013
07:11ARL Spectral Fitting as an Application to Augment Spectral Data via Franck-Condon Lineshape Analysis and Color Analysis
Published on: August 19, 2021
