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Updated: Jun 12, 2025

Controlled Photoredox Ring-Opening Polymerization of O-Carboxyanhydrides Mediated by Ni/Zn Complexes
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Directional Ring Translocation in a pH- and Redox-Driven Tristable [2]Rotaxane

Leonardo Andreoni1,2, Jessica Groppi2,3, Özlem Seven2,3

  • 1Dipartimento di Chimica Industriale "Toso Montanari", Università di Bologna, viale del Risorgimento 4, 40136, Bologna, Italy.

Angewandte Chemie (International Ed. in English)
|September 20, 2024
PubMed
Summary

Researchers developed a novel rotaxane molecule with three recognition sites. Its macrocycle can be precisely controlled along the axle using orthogonal stimuli, paving the way for molecular machines.

Keywords:
AmmoniumBypiridiniumCrown ethersMolecular MachinesRotaxanesTriazolium

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