The N,N,N',N'-tetraphenylbenzidine-based conjugated hypercrosslinked polymers for adsorping iodine and fluorescence...

Although progress has been made in the development of hypercrosslinked polymers (HCPs) for iodine uptake, their fluorescence performance and fluorescence sensing performance are rare due to the lack of conjugated behavior in common HCPs. Herein, the N,N,N',N'-tetraphenylbenzidine-based conjugated hyper-crosslinked polymers (conjugated TPB-based HCPs) were efficiently fabricated via a one-step Friedel-Crafts arylation reaction by selecting N,N,N',N'-tetraphenylbenzidine (TPB) and N,N'-diphenyl-N,N'-di(m-tolyl)benzidine (DPDB) as the basic building blocks and p-dimethoxybenzene (DMB) as an external crosslinker which will lead to the formation of the conjugated structures. The derived TPB-based HCPs (denoted as, TPB-DMB and DPDB-DMB) possessed excellent stability and high surface areas, Their iodine adsorption capacities are up to 4.25 and 3.56 g·g^-1. The high iodine adsorption is caused by chemical adsorption. The fully conjugated structure and the 3D aryl network give the conjugated TPB-based HCPs excellent luminescence properties and fluorescence sensing properties for 2,4-dinitrophenol and iodine. The fluorescence sensing mechanisms of the conjugated  TPB-based HCPs for DNP and I₂ includes photo-induced electron process and the resonance energy transfer process. This study provides a viable approach for the development of highly efficient iodine sorbents and fluorescence sensors of DNP and iodine for addressing environmental issues.