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Partially amorphous NiFe layered double hydroxides enabling highly-efficiency oxygen evolution reaction at high

Guijin Yang1, Dongyang Fang1, Yujun Fu2

  • 1Key Laboratory of Atomic and Molecular Physics & Functional Materials of Gansu Province, College of Physics and Electronic Engineering, Northwest Normal University, Lanzhou 730070, PR China.

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|September 22, 2024
PubMed
Summary

This study combines amorphous and crystalline NiFe layered double hydroxide (LDH) to enhance water electrolysis catalysts. The new LDH catalyst demonstrates superior oxygen evolution reaction (OER) activity and stability for commercial applications.

Keywords:
AmorphousHigh current densityLattice oxygen mechanismNiFe LDHOxygen evolution reaction

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Area of Science:

  • Materials Science
  • Electrochemistry
  • Catalysis

Background:

  • Layered double hydroxides (LDHs) are promising electrocatalysts for water electrolysis.
  • Challenges include low electrical conductivity and limited active site accessibility in LDHs.
  • Optimizing LDH structure is crucial for efficient oxygen evolution reactions (OER).

Purpose of the Study:

  • To enhance the performance and stability of NiFe LDH catalysts for OER.
  • To combine amorphous and crystalline structures in NiFe LDH.
  • To investigate the impact on catalytic activity, mechanism, and kinetics.

Main Methods:

  • Synthesized NiFe LDH by combining disordered amorphous and ordered crystalline phases.
  • Characterized the catalyst's structure and properties.
  • Evaluated electrocatalytic performance for OER under alkaline conditions.

Main Results:

  • The combined structure improved intrinsic activity and shifted the OER mechanism to the lattice oxygen mechanism (LOM).
  • Achieved an ultralow overpotential of 189 mV at 10 mA cm⁻² with a Tafel slope of 43 mV dec⁻¹.
  • Demonstrated excellent stability over 80 hours at 1 A cm⁻².

Conclusions:

  • The novel NiFe LDH catalyst offers enhanced activity and stability for OER.
  • The strategy effectively addresses conductivity and active site accessibility issues.
  • This approach shows potential for commercialization in water electrolysis.