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Updated: Jun 12, 2025

Preparation and Reactivity of a Triphosphenium Bromide Salt: A Convenient and Stable Source of PhosphorusI
Published on: November 22, 2016
Adducts of Lewis acidic stibanes with phosphane chalcogenides
Jonas Krieft1, Hannah Koch1, Beate Neumann1
1Chair of Inorganic and Structural Chemistry, Center for Molecular Materials CM2, Faculty of Chemistry, Bielefeld University, Universitätsstraße 25, 33615 Bielefeld, Germany. mitzel@uni-bielefeld.de.
Abstract:
Starting from ClSbRF2 (RF = C2F5, 3,5-(CF3)2C6H3) and H(E)P(tBu)2 (E = O, S), we prepared the oxy- and sulphanediyl-bridged adducts RF2Sb(Cl)-E-(H)P(tBu)2, which are stable against the elimination of HCl. The different electron-withdrawing substituents and chalcogen bridging units influence the size of the Sb-E-P angle. ClSb(C2F5)2 and nBu3SnH react to give HSb(C2F5)2, which seems to interact weakly with H(O)P(tBu)2 in solution as observed via NMR. All products were characterised by NMR spectroscopy and all the stable ones were additionally characterised by X-ray diffraction and elemental analyses.
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