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Phase Transitions: Melting and Freezing02:39

Phase Transitions: Melting and Freezing

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Heating a crystalline solid increases the average energy of its atoms, molecules, or ions, and the solid gets hotter. At some point, the added energy becomes large enough to partially overcome the forces holding the molecules or ions of the solid in their fixed positions, and the solid begins the process of transitioning to the liquid state or melting. At this point, the temperature of the solid stops rising, despite the continual input of heat, and it remains constant until all of the solid is...
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When water is poured into a glass, it falls freely and quickly, whereas if honey or maple syrup is poured over a pancake, it flows slowly and sticks to the surface of the container. This difference in the flow of different kinds of liquids arises due to the fluid friction between the liquid layers and the liquid and the surrounding material. This property of fluids is called fluid viscosity. In this example, water has a lower viscosity than honey and maple syrup.
The SI unit of viscosity is...
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A pure, perfectly crystalline solid possessing no kinetic energy (that is, at a temperature of absolute zero, 0 K) may be described by a single microstate, as its purity, perfect crystallinity,and complete lack of motion means there is but one possible location for each identical atom or molecule comprising the crystal (W = 1). According to the Boltzmann equation, the entropy of this system is zero.
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Polymer Classification: Crystallinity01:21

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Unlike ionic or small covalent molecules, polymers do not form crystalline solids due to the diffusion limitations of their long-chain structures. However, polymers contain microscopic crystalline domains separated by amorphous domains.
Crystalline domains are the regions where polymer chains are aligned in an orderly manner and held together in proximity by intermolecular forces. For example, chains in the crystalline domains of polyethylene and nylon are bound together by van der Waals...
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When a substance—isolated from its environment—is subjected to heat changes, corresponding changes in temperature and phase of the substance is observed; this is graphically represented by heating and cooling curves.
For instance, the addition of heat raises the temperature of a solid; the amount of heat absorbed depends on the heat capacity of the solid (q = mcsolidΔT). According to thermochemistry, the relation between the amount of heat absorbed or released by a substance, q, and its...
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Phase Transitions02:31

Phase Transitions

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Whether solid, liquid, or gas, a substance's state depends on the order and arrangement of its particles (atoms, molecules, or ions). Particles in the solid pack closely together, generally in a pattern. The particles vibrate about their fixed positions but do not move or squeeze past their neighbors. In liquids, although the particles are closely spaced, they are randomly arranged. The position of the particles are not fixed—that is, they are free to move past their neighbors to...
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Related Experiment Video

Updated: Jun 12, 2025

Orientational Transition in a Liquid Crystal Triggered by the Thermodynamic Growth of Interfacial Wetting Sheets
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Orientational Transition in a Liquid Crystal Triggered by the Thermodynamic Growth of Interfacial Wetting Sheets

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Thermally activated intermittent flow in amorphous solids.

Daniel James Korchinski1, Jörg Rottler1

  • 1Department of Physics and Astronomy and Quantum Matter Institute, University of British Columbia, 2355 East Mall, Vancouver, BC V6T 1Z1, Canada. djkorchi@phas.ubc.ca.

Soft Matter
|September 25, 2024
PubMed
Summary
This summary is machine-generated.

This study reveals that standard rheological flow laws for amorphous solids break down under intermittent flow conditions. A new thermal activation stress scale governs flow behavior in this regime, necessitating a re-evaluation of slow shearing effects.

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Area of Science:

  • Condensed Matter Physics
  • Materials Science
  • Rheology

Background:

  • Amorphous solids exhibit complex flow behavior under shear.
  • Existing rheological models often assume continuous flow, which may not apply universally.

Purpose of the Study:

  • To analyze the steady-state shear rheology of amorphous solids, particularly focusing on thermally activated processes.
  • To identify how rheological flow laws change in the intermittent flow regime.

Main Methods:

  • Application of mean field theory.
  • Utilizing a mesoscale elastoplastic model.
  • Analysis of thermally activated amorphous solids under shear.

Main Results:

  • Continuous flow is described by established laws (e.g., Herschel-Bulkley) at high temperatures and driving rates.
  • Intermittent flow, characterized by serrated behavior, requires a revised understanding.
  • A thermal activation stress scale, x_a(T, γ̇), unifies the effects of temperature and driving rate on flow stress and event sizes.

Conclusions:

  • Standard rheological laws are insufficient for intermittent flow in amorphous solids.
  • The identified thermal activation stress scale provides a universal descriptor for this regime.
  • Further investigation into the rheology of slowly sheared amorphous matter below the glass transition is warranted.