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Updated: Jun 11, 2025

Synthesis and Purification of Iodoaziridines Involving Quantitative Selection of the Optimal Stationary Phase for Chromatography
Published on: May 16, 2014
Investigation of Electrocatalytic Oxidative Coupling of Arylamines for the Selective Synthesis of Azo Aromatics
Pooja Soam1, Vikas Tyagi1,2
1Department of Chemistry and Biochemistry, Thapar Institute of Engineering and Technology, Patiala 147004, Punjab, India.
Abstract:
An electrochemical oxidative coupling of anilines to selectively provide azo aromatic compounds by using mild reaction conditions has been investigated. Further, the generality and feasibility of the developed protocol were showcased by synthesizing differently substituted azo compounds in moderate to good isolated yields. Additionally, different control experiments were performed to investigate the reaction mechanism. These experiments indicated the formation of hydrazobenzene as an intermediate while ruling out the possibility of nitrobenzene or nitroso-benzene formation during this transformation.
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