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Updated: Jun 11, 2025

Tuning Oxide Properties by Oxygen Vacancy Control During Growth and Annealing
Published on: June 9, 2023
Oxygen vacancies in Bi2WO6 enable robust nitrate reduction reaction catalysis
Qing Ren1, Cong Zhou2,3, Yumei Feng3
1College of Chemical and Textile Engineering, Xinjiang University of Science and Technology, Korla, 841000, Xinjiang, China.
Abstract:
The faradaic efficiency of Bi2WO6 is 62.0% at -0.3 V vs. RHE, an improvement of 1.4- and 1.8-times relative to Bi2O3 and WO3 for the nitrate reduction reaction. In addition, the catalysis occurring on Bi2WO6 follows the pathway: *NO3-*NO2-*NO-*NOH-*HNOH-*H2NOH-*NH3, as verified by operando Raman spectroscopy and theoretical calculations.
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