Synthesis, Structural Characterization and Catalytic Application of Ferrocenyl Based Bis(pyrazolyl) Palladium
Sushanta Kumar Meher1, Basava Punna Rao Aradhyula1, Venkateswara Rao Velpuri1,2
1School of Chemical Sciences, National Institute of Science Education and Research (NISER), Bhubaneswar, an OCC of Homi Bhabha National Institute, Bhubaneswar, Odisha, 752050, India.
Abstract:
Here we report, synthesis of ferrocenyl based bis(pyrazolyl) palladium complexes. The catalytic utility of the complexes in the cross-coupling of triarylbismuthanes and aryl bromides was evaluated. Our ferrocenyl based palladium complex showed wide substrate scope for both triarylbismuthanes and aryl bromides. Further, the current catalytic system also showed superior activity over the well-established palladium-phosphine catalytic system using triarylbismuthanes as reagents.
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