Factors influencing the dissolution rate of radon gas in water

Measurements of radon (²²²Rn) in water are widely utilized across various disciplines, including technology, medicine, exploration, and ecological preservation. For accurate radon measurements in water, the availability of a standardized radon solution is essential. Researchers have predominantly concentrated on the radon concentration in water (RCW) once radon distribution equilibrium is achieved, rather than the rate of radon dissolution prior to equilibrium, in the development of standard radon solutions. This makes the preparation speed of the calibration standards radon solution slow, which seriously restricts the research and development of the standard device. The purpose of this paper is to investigate the correlation between the rate of radon dissolution and both the concentration of gaseous radon and the stirring speed. Four conclusions have been derived through univariate analysis. ➀ The radon concentration in water (RCW) increases with the duration of radon dissolution, eventually reaching a state of equilibrium. ➁ The increase in gas radon concentration correlates with a simultaneous rise in the rate of radon dissolution, while the time required for radon distribution equilibrium remains constant. ➂ The augmentation of the stirring speed enhances the rate of radon dissolution, Concurrently reducing the time needed for RCW to reach equilibrium.➃ When the stirring speed is excessively high, it results in substantial fluctuations in both RCW and the rate of radon dissolution. Consequently, when employing this method for the preparation of radon solutions, it is advisable to regulate the duration of radon dissolution to 30 min at a rate of 380 rad/min and 10 min at a rate of 480 rad/min. This regulation ensures the attainment of precise concentrations. Under conditions of environmental stability, manipulation of gas radon concentration alone proves sufficient for adjusting RCW . These empirical findings furnish a robust foundation for the efficient preparation of standardized radon solutions and the requisite apparatus, essential for the calibration and accuracy of radon measurement instruments.